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1d947889e4 Oliv*0001 .. include:: ../defs.hrst
                0002 
                0003 Model equations
                0004 ^^^^^^^^^^^^^^^
                0005 
faa67d1773 Oliv*0006 The basic model equations are (omitting transport terms handled by the ptracers
3c930300af Oliv*0007 package, :ref:`para_phys_pkg_darwin_sink`, :ref:`AirSea` and terms correcting
                0008 conservation with the linear free surface formulation discussed in
                0009 :numref:`para_phys_pkg_darwin_cons`):
1d947889e4 Oliv*0010 
                0011 .. math::
                0012 
ab3dad0141 Oliv*0013    \partial_t\op{DIC}   &= \sum_j \bigl( (-U^{\mathrm{DIC}}_j + R^{\mathrm{C}}_j)
81872c4188 Oliv*0014                                          \cdot (1 + R^{\text{PIC:POC}}_j)
ab3dad0141 Oliv*0015                                          + R^{\mathrm{DIC}}_j
81872c4188 Oliv*0016                                   \bigr)
ab3dad0141 Oliv*0017                            + R_{\mathrm{DOC}} + [R_{\mathrm{POC}}]
3c930300af Oliv*0018                            + D_{\mathrm{PIC}} \\
ab3dad0141 Oliv*0019    \partial_t\op{PO}_4  &= \sum_j \bigl( -U^{\mathrm{PO4}}_j + R^{\mathrm{P}}_j + R^{\mathrm{PO4}}_j \bigr)
                0020                            + R_{\mathrm{DOP}} + [R_{\mathrm{POP}}] \\
                0021    \partial_t\op{NH}_4  &= \sum_j \bigl( -U^{\mathrm{NH4}}_j + R^{\mathrm{N,NH4}}_j + R^{\mathrm{NH4}}_j \bigr)
                0022                            + R_{\mathrm{DON}} + [R_{\mathrm{PON}}] - P_{\mathrm{NO2}} - D_{\mathrm{NH4}} \\
                0023    \partial_t\op{NO}_2  &= \sum_j \bigl( -U^{\mathrm{NO2}}_j + R^{\mathrm{N,NO2}}_j + R^{\mathrm{NO2}}_j \bigr)
                0024                            + P_{\mathrm{NO2}} - P_{\mathrm{NO3}} \\
                0025    \partial_t\op{NO}_3  &= \sum_j \bigl( -U^{\mathrm{NO3}}_j + R^{\mathrm{N,NO3}}_j + R^{\mathrm{NO3}}_j \bigr)
                0026                            + P_{\mathrm{NO3}} - D_{\mathrm{NO3}} \\
                0027    \partial_t\op{FeT}   &= \sum_j \bigl( -U^{\mathrm{Fe}}_j + R^{\mathrm{Fe}}_j + R^{\mathrm{FeT}}_j \bigr)
                0028                            + R_{\mathrm{DOFe}} + [R_{\mathrm{POFe}}] + S_{\mathrm{Fe}} \\
                0029    \partial_t\op{SiO}_2 &= \sum_j \bigl( -U^{\mathrm{SiO2}}_j + R^{\mathrm{Si}}_j \bigr)
                0030                            + R_{\mathrm{POSi}} \\
                0031    \partial_t c_j       &= U^{\mathrm{DIC}}_j - M_j - R^{\mathrm{C}}_j - G_j + g_j^{\mathrm{C}} \\
                0032    \partial_t p_j       &= U^{\mathrm{PO4}}_j - M_j Q^{\mathrm{P}}_j - G_j Q^{\mathrm{P}}_j + g_j^{\mathrm{P}}          \qquad\text{(with P quota)} \\
                0033    \partial_t n_j       &= U^{{\mathrm{N}}}_j \;\;\; - M_j Q^{\mathrm{N}}_j - G_j Q^{\mathrm{N}}_j + g_j^{\mathrm{N}}   \qquad\text{(with N quota)} \\
                0034    \partial_t\op{fe}_j  &= U^{\mathrm{Fe}}_j \;\; - M_j Q^{\mathrm{Fe}}_j - G_j Q^{\mathrm{Fe}}_j + g_j^{\mathrm{Fe}}   \qquad\text{(with Fe quota)} \\
                0035    \partial_t\op{si}_j  &= U^{\mathrm{SiO2}}_j - M_j Q^{\mathrm{Si}}_j - G_j Q^{\mathrm{Si}}_j                          \qquad\text{(with Si quota)} \\
                0036    \partial_t\op{Chl}_j &= S^{\mathrm{Chl}}_j \; - M_j Q^{\mathrm{Chl}}_j - G_j Q^{\mathrm{Chl}}_j                      \qquad\text{(with Chl quota)} \\
                0037    \partial_t\op{DOC}   &= \sum_j M_j^{\mathrm{DOM}} \;\;\;\;\;         + g^{\mathrm{DOC}}  + \sum_j \left( H^{\mathrm{POC}}_j - U^{\mathrm{DOC}}_j \right) - R_{\mathrm{DOC}} - S_{\mathrm{CDOM}} R^{{\mathrm{C}}:{\mathrm{P}}}_{\mathrm{CDOM}} \\
                0038    \partial_t\op{DOP}   &= \sum_j M_j^{\mathrm{DOM}} Q_j^{{\mathrm{P}}} + g^{\mathrm{DOP}}  + \sum_j \left( H^{\mathrm{POP}}_j - U^{\mathrm{DOP}}_j \right) - R_{\mathrm{DOP}} - S_{\mathrm{CDOM}} \\
                0039    \partial_t\op{DON}   &= \sum_j M_j^{\mathrm{DOM}} Q_j^{{\mathrm{N}}} + g^{\mathrm{DON}}  + \sum_j \left( H^{\mathrm{PON}}_j - U^{\mathrm{DON}}_j \right) - R_{\mathrm{DON}} - S_{\mathrm{CDOM}} R^{{\mathrm{N}}:{\mathrm{P}}}_{\mathrm{CDOM}} \\
                0040    \partial_t\op{DOFe}  &= \sum_j M_j^{\mathrm{DOM}} Q_j^{\mathrm{Fe}}      + g^{\mathrm{DOFe}} + \sum_j \left( H^{\mathrm{POFe}}_j- U^{\mathrm{DOFe}}_j\right) - R_{\mathrm{DOFe}}- S_{\mathrm{CDOM}} R^{{\mathrm{Fe}}:{\mathrm{P}}}_{\mathrm{CDOM}} \\
3c930300af Oliv*0041    \partial_t\op{PIC}   &= \sum_j M_j     R_j^{\text{PIC:POC}}      + g^{\mathrm{PIC}} - D_{\mathrm{PIC}} \\
ab3dad0141 Oliv*0042    \partial_t\op{POC}   &= \sum_j M_j^{\mathrm{POM}} \;\;\;\;\;         + g^{\mathrm{POC}}  - \sum_j U^{\mathrm{POC}}_j  - R_{\mathrm{POC}} \\
                0043    \partial_t\op{POP}   &= \sum_j M_j^{\mathrm{POM}} Q_j^{{\mathrm{P}}} + g^{\mathrm{POP}}  - \sum_j U^{\mathrm{POP}}_j  - R_{\mathrm{POP}} \\
                0044    \partial_t\op{PON}   &= \sum_j M_j^{\mathrm{POM}} Q_j^{{\mathrm{N}}} + g^{\mathrm{PON}}  - \sum_j U^{\mathrm{PON}}_j  - R_{\mathrm{PON}} \\
                0045    \partial_t\op{POFe}  &= \sum_j M_j^{\mathrm{POM}} Q_j^{\mathrm{Fe}}      + g^{\mathrm{POFe}} - \sum_j U^{\mathrm{POFe}}_j - R_{\mathrm{POFe}} \\
                0046    \partial_t\op{POSi}  &= \sum_j M_j Q_j^{\mathrm{Si}} \;\;\;\;\;      + g^{\mathrm{POSi}}                          - R_{\mathrm{POSi}} \\
                0047    \partial_t\op{ALK}   &= -\biggl( P_{\mathrm{NO3}} - \sum_j U^{\mathrm{NO3}}_j \biggr)
3c930300af Oliv*0048        - 2\biggl( \sum_j U^{\mathrm{DIC}}_j R^{{\text{PIC:POC}}}_j - D_{\mathrm{PIC}} \biggr)
ab3dad0141 Oliv*0049        + D_{\mathrm{NO3}} \\
faa67d1773 Oliv*0050    \partial_t{\mathrm{O}}_2 &= R_{\mathrm{O}_2:\mathrm{P}} \biggl(
ab3dad0141 Oliv*0051                                    \sum_j U^{\mathrm{PO4}}_j
                0052                                    - R_{\mathrm{DOP}} - [R_{\mathrm{POP}}]
faa67d1773 Oliv*0053                                \biggr)
                0054    \\
ab3dad0141 Oliv*0055    \partial_t\op{CDOM}  &= S_{\mathrm{CDOM}} \qquad\text{(with CDOM tracer)} \\
faa67d1773 Oliv*0056 
1d947889e4 Oliv*0057 
ab3dad0141 Oliv*0058 The quotas are defined as :math:`Q^{\mathrm{P}}_j=p_j/c_j`, etc.  The following
                0059 abbreviated source terms are described in sections below:
1d947889e4 Oliv*0060 
faa67d1773 Oliv*0061 - :math:`U`: uptake, see :ref:`Uptake` and :ref:`Bacteria`,
8916dab93b Oliv*0062   also :ref:`Growth`, :ref:`CarbonStore`, :ref:`Light` and :ref:`Spectral`
81872c4188 Oliv*0063 - :math:`M`: :ref:`Mortality`
51e33025af Oliv*0064 - :math:`R^{\mathrm{C}}`, :math:`R^{\mathrm{P}}`, ...: :ref:`Respiration`
                0065 - :math:`H`, :math:`R^{\mathrm{DIC}}`, ...: bacterial hydrolysis and remineralization, see :ref:`Bacteria`
faa67d1773 Oliv*0066 - :math:`R`, :math:`P`: parameterized :ref:`Remineralization`
3c930300af Oliv*0067 - :math:`D_{\mathrm{NO3}}`: denitrification, see :ref:`Denitrification`
                0068 - :math:`D_{\mathrm{PIC}}`: dissolution of PIC, see :ref:`CarbonChemistry`
faa67d1773 Oliv*0069 - :math:`g`, :math:`G`: grazing gains and losses, see :ref:`Grazing`
ab3dad0141 Oliv*0070 - :math:`S^{\mathrm{Chl}}`: synthesis, see :ref:`Synthesis`
                0071 - :math:`S_{\mathrm{Fe}}`: iron sources, see :ref:`Iron`
                0072 - :math:`S_{\mathrm{CDOM}}`: see :ref:`CDOM`.
1d947889e4 Oliv*0073 
faa67d1773 Oliv*0074 With :varlink:`DARWIN_ALLOW_CDOM`, all particulate remineralization terms
                0075 (in square brackets [...]) except Si are absent.
ab3dad0141 Oliv*0076 Without :varlink:`DARWIN_ALLOW_CDOM`, :math:`f_{\mathrm{CDOM}}=0` and there is no CDOM tracer.
3c930300af Oliv*0077 The Alk and O\ :sub:`2` tracers are only present with :varlink:`DARWIN_ALLOW_CARBON`.
1d947889e4 Oliv*0078 
a4f2018aab Oliv*0079 
                0080 .. csv-table:: General parameters
                0081    :delim: &
faa67d1773 Oliv*0082    :widths: 15,17,14,11,18,25
a4f2018aab Oliv*0083    :class: longtable
                0084    :header: Trait, Param, Symbol, Default, Units, Description
                0085 
ab3dad0141 Oliv*0086    :varlink:`R_PICPOC` & :varlink:`a_R_PICPOC` & :math:`R^{\text{PIC:POC}}_j`              & 0.8          & mmol PIC / mmol POC       & inorganic-organic carbon ratio
                0087                        & :varlink:`R_OP`       & :math:`R_{\mathrm{O}_2:\mathrm{P}}`       & 170          & mmol O\ :sub:`2` / mmol P & O\ :sub:`2`:P ratio for respiration and consumption
a4f2018aab Oliv*0088 
ab3dad0141 Oliv*0089 For CDOM elemental ratios, see :ref:`CDOM`.
3b34245348 Oliv*0090 
                0091 Flow diagrams for the various chemical elements:
                0092 
                0093 .. figure:: figs/darwin_P_noCDOM_nograz.*
                0094    :width: 100%
                0095    :align: center
                0096    :alt: Flow of phosphorus schematic
                0097    :name: figdarwinP
                0098 
                0099    The flow of phosphorus without CDOM (for grazing see :numref:`figdarwinPgraz`)
                0100 
                0101 .. figure:: figs/darwin_P_CDOM_nograz.*
                0102    :width: 100%
                0103    :align: center
                0104    :alt: Flow of phosphorus schematic
                0105    :name: figdarwinPCDOM
                0106 
1b4f0c760e Oliv*0107    The flow of phosphorus with CDOM.
3b34245348 Oliv*0108 
                0109 .. figure:: figs/darwin_P_graz.*
                0110    :width: 75%
                0111    :align: center
                0112    :alt: Flow of phosphorus schematic
                0113    :name: figdarwinPgraz
                0114 
                0115    The flow of phosphorus due to grazing.
                0116 
                0117 .. figure:: figs/darwin_N_noCDOM_nograz.*
                0118    :width: 100%
                0119    :align: center
                0120    :alt: Flow of nitrogen schematic
                0121    :name: figdarwinN
                0122 
                0123    The flow of nitrogen (no CDOM, grazing suppressed).
                0124 
                0125 .. figure:: figs/darwin_Fe_noCDOM_nograz.*
                0126    :width: 100%
                0127    :align: center
                0128    :alt: Flow of iron schematic
                0129    :name: figdarwinFe
                0130 
                0131    The flow of iron (no CDOM, grazing suppressed).
                0132 
                0133 .. figure:: figs/darwin_Si_noCDOM_nograz.*
                0134    :width: 80%
                0135    :align: center
                0136    :alt: Flow of silica schematic
                0137    :name: figdarwinSi
                0138 
                0139    The flow of silica (no CDOM, grazing suppressed).
                0140 
                0141 .. figure:: figs/darwin_ALK.*
                0142    :width: 50%
                0143    :align: center
                0144    :alt: Flow of alkalinity schematic
                0145    :name: figdarwinALK
                0146 
                0147    Sources and sinks of alkalinity.
                0148 
                0149 .. figure:: figs/darwin_O2.*
                0150    :width: 50%
                0151    :align: center
                0152    :alt: Flow of oxygen schematic
                0153    :name: figdarwinO2
                0154 
                0155    Sources and sinks of oxygen.